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Best practice for monitoring coin cell battery voltage given ESR

I'm using an NRF51 w/ S130 operated directly from a coin cell battery. I use the ADC with a voltage divider to successfully measure analog voltages. One of the challenges of the coin cell is that its ESR is not insignificant and degrades overtime. This means that if I have a substantial current pulse (for example from RF activity) the battery voltage droops in a meaningful way (sometimes ~200 mV). The ESR is not fixed and usually gets worse over time. Suppose my system cannot operate below 2.4V and I want to monitor the battery voltage and [do something] when there's a low battery condition. What's the best way to do this given the ESR? For example with a multimeter I might see "2.6V", but with a healthy current pulse the battery might actually droop to 2.4 momentarily, which could brownout my system. Is there a way to synchronize sampling the ADC with RF activity so I can measure the worst case battery voltage?

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